Rescuers should be taken for medical attention if necessary. Hydrogen is a colorless, odorless, flammable gas or a colorless, odorless, cryogenic liquid. Information contained in this material safety data sheet msrds is believed to be reliable but no representation, guarantee or warranties of any kind are made as to accuracy, suitability for a particular application or results to be obtained from them. Gas cabinets, with appropriate exhaust treatment, are recommended, as is automatic monitoring of the secondary enclosures and work areas for release. Osha, cma, ansi and canadian whmis standards part i what is the material and what do i need to know in an emergency. Electrical equipment should be nonsparking or explosion proof. Praxair material safety data sheet see section 15, under tsca, for important restrictions on product use. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
All hazard information pertinent to this product has been provided in this material safety data sheet, per the requirements of the federal occupational safety and health administration standard 29 cfr 1910. Safety data sheet carbon monoxide air liquidegasekatalog. Irrigate eyes for at least 15 minutes with copious quantities of water, keeping eyelids apart and away from. Never recompress a gas or a gas mixture without first consulting the. Never recompress a gas or a gas mixture without first consulting the supplier. Irrigate eyes for at least 15 minutes with copious quantities of water, keeping eyelids apart and away from eyeballs during irrigation.
Do not extinguish, unless leak can be stopped safely. Read and follow all safety data sheets sdss before use. Liquefied natural gas, material safety data sheet, revision date, page 4 11. When involved in a fire, this gas will ignite and produce toxic gases including carbon monoxide. Ne not established c ceiling limit see section 16 for definitions of terms used. Includes tips on safe handling, and information useful to emergency response and other medical personnel. Nitrogen is not listed as a marine pollutant by dot. Structural firefighters protective clothing provides limited protection in fire. Precautionary statements prevention keep away from heat, sparks, open flames andor hot surfaces.
Relevant identified uses of the subs tance or mixture and uses advised against use of the substancemixture. If you have questions or concerns about the whmis legislation, please contact your local ministry of labour office. Conditions for safe storage, including any incompatibilities. Msa pn 10028062 calibration check gas, 40 ppm hydrogen. Compressed gas high concentrations may exclude oxygen and cause dizziness and suffocation.
Move containers from fire area if you can do it without risk. Refrigerated liquefied gas h281 simple asphyxiant hazards not otherwise classified health hazard frostbite label elements osha hcs 2012 danger hazard statements extremely flammable gas h220 contains refrigerated gas. Cylinders should be stored upright with valve protection cap in place and firmly secured to prevent falling. Nitrous oxide, compressed safety data sheet p4636 this sds conforms to u. Safety data sheet ghs product identifier other means of identification product type section 1. Compressed gas h280 classification according to whs regulation 1.
Methane is inactive biologically and essentially nontoxic. Take a copy of the label and the msds to physician or other health professional with victims. Most important symptoms and effects, both acute and delayed eye contact direct contact with this liquefied gas may burn the eyes. Chemical product and company identification product name. Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. An overview of the chemical make up and identifies the many procedures and proper handling of natural gas. Your new online msds binder is a place for you to store the. P271 use only outdoors or in a wellventilated area. Details of the supplier of the safety data sheet praxair, inc. Msa pn 10028062 calibration check gas, 40 ppm hydrogen sulfide in nitrogen msds. Nitrogen is a colorless, odorless, nonflammable gas, or a colorless, odorless, cryogenic liquid.
Inhalation inhaling the vapour may cause drowsiness and dizziness. Shipment of compressed gas cylinders that have been filled without the owners consent is a violation of federal law 49 cfr 173. Other companies are charging thousands of dollars to set up accounts and give you access to. Relevant identified uses of the substance or mixture and uses advised against use of the substancemixture. Remove containers from area of fire if safe to do so. Material safety data sheet hydrofluoric acid, anhydrous msds number. Identification product identifier product name natural gas synonyms natural gasdry. Gas detection equipment should be used, particularly when working in confined areas. Gas fires should not be extinguished unless flow of gas can be immediately stopped. Primarily methane gas with other fossil fuels such as ethane, propane, butane and pentane.
Shipment of compressed gas cylinders that have been filled without the owner. For additional recommendations consult compressed gas associations cga safety bulletin sb2, oxygendeficient atmospheres. Nitrous oxide, compressed weizmann institute of science. Hydrogen, compressed gas safety data sheet sds p4604.
Dihydrogen, parahydrogen, refrigerant gas r702, water gas 1. Wear positive pressure selfcontained breathing apparatus scba. Exposure controls personal protection engineering measures provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below. Safety data sheet natural gas southern california gas. Earthground and bond all lines and equipment associated with the hydrogen system. The main health hazard associated with releases of this gas is asphyxiation, by displacement of oxygen. A cylinder rupture hazard exists when this gas mixture, which is under pressure, is subject to heat or flames.
Never attempt to transfer gases from one cylindercontainer to another. Calibration gas sds calibration gas mixture sds supplier. This msds is also available electronically on our website. Section 2 hazards identification ghs classification flammable gas, category 1 gas under pressure, compressed gas acute toxicity inhalation, category 4 95% unknown ghs label elements symbols signal word danger. Handle sealed gas cylinders in accordance with cga p1, safe handling of compressed gases in. Under certain conditions, the distinctive odorant added to natural gas may be diminished or lost so that it cannot be smelled. Skin contact contact with the product may cause frostbite. Wear appropriate respirator when ventilation is inadequate.
Below is a list of our most common calibration gas mixtures sdss. Store in cool, dry, wellventilated area of noncombustible. Pipeline gas sds numbergrade ng 200801 relevant identified uses of the substance or mixture and uses advised against. Other exposure guidelines vacated limits revoked by the court of appeals decision in aflcio v. The suitability of this product as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the physiological effects, methods employed. If irritation of the skin develops after exposure to this gas mixture, immediately begin decontamination with. Methane is not listed in the iarc, ntp or by osha as a carcinogen or potential carcinogen. P210 wear cold insulating gloves, face shield andor eye protection. Download the safety nitnem path in pdf data sheets sds for boc products gases, to ensure you and your team are well informed.
Perpaerd may 205 1 material safety data sheet for natural gas hazardous ingredients. May cause skin, eye, and respiratory tract irritation asphyxiant at high concentrations may cause central nervous system depression contents under pressure keep at temperatures below 52c 125f material safety data sheet. Details of the supplier of the safety data sheet emergency telephone number 2. Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and smoking should be prohibited in areas where this material is. For additional recommendations consult compressed gas associations cga. Relevant identified uses of the substance or mixture and uses advised against 1. Identification product identifier product name natural gas synonyms natural gas dry. Dihydrogen, parahydrogen, refrigerant gas r702, water gas.
Cgapg02 protect from sunlight when ambient temperature exceeds 52c 125f. Our calibration gas sds information includes material identification, physicalchemical characteristics, fire and exposure hazardous data, reactivity hazardous data, precautions for safe handling and use, and control measures. Material safety data sheet southern california gas company. In case of frostbite, obtain immediate medical attention. Msds material safety data sheet for gaseous hydrogen h2 by universal industrial gases, inc. Humans breathing up to 8 ppm of hydrogen sulfide over a two month period experienced nausea, headache, shortness of breath, sleep disturbance, eye and throat irritation.
If involved in a major fire, they should be sprayed with water to. Use water spray to cool surroundings and exposures. None of the trace impurities of this gas contribute significantly to the hazards associated with the product. Firefighting measures these containers hold gas under pressure, with no liquid phase. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Nitrogen, gas, material safety data sheet, revision date 31aug2010, page 3 8. P280 wear eye protection, face protection, protective gloves, protective clothing. Do not rely on sense of smell alone to determine if there is a gas leak or if gas is otherwise present. Disclaimer statement this information is furnished without warranty, expressed or implied, as to accuracy or completeness.
Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and. Nitrous oxide, compressed safety data sheet sds p4636. Stop flow of gas if safe to do so, while continuing cooling water spray. The information is obtained from various sources including the. Material safety data sheet gasoline, all grades msds no. Gas compressed gas contains gas under pressure may. Material safety data sheet imperial college london. A hazard from reignition or explosion exists if the flame is extinguished without stopping flow of gas andor cooling surroundings and eliminating ignition source. The main health hazard associated with releases of this gas is asphyxiation, by displacement of.
1409 803 1343 930 1485 668 1310 957 1075 1480 802 1231 958 17 1210 507 1205 742 94 528 202 705 1023 1353 227 120 182 277